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You can purchase this spice in most well-stocked grocery stores or you can make your own.

A combination of cayenne pepper, cinnamon, and ground cloves can be a workable substitute for five-spice powder as it covers most of the five.

Instead, add a splash of sambuca to your dish. Another option is to do away with powdered spices altogether.
Chinese Five Spice (5-spice) is a spice mixture commonly used in Chinese cooking.

It is also common to include black pepper and ground ginger, so the exact recipe is best left up to taste. A more specific recipe for a Chinese five-spice substitute using preground spices is a combination of 2 tablespoons ground anise, 1 tablespoon ground fennel, 2 teaspoons ground cinnamon and a scant teaspoon of ground cloves. It is a combination of cinnamon, cloves, fennel seed, star anise and szechuan peppercorns.

Homemade Five-Spice Powder Using Whole Spices An easy way to make a substitute for Five Spice Powder is to mix equal parts of anise, cinnamon, clove, fennel and Szechuan peppercorns.